Under double influence from the relocation for poverty alleviation and the rural tourism development,relocated peasant households in minority areas have encountered an opportunity of livelihood transformation. However, constraints from living funds, psychological barriers and tourism development bottlenecks have weakened to a certain extent the relocated peasant households' motivation for livelihood transformation and have affected their livelihood transformation process. To overcome these obstacles, the government should reallocate the critical living funds to enhance relocated peasant households' abilities to participate in tourism activities, increase the supply of psychological resources to boost relocated peasant households' willingness to participate in tourism activities, and renew tourism development vitality to realize the sustainability of tourism livelihood mode.