To investigate the present status of academic emotions and the relationship with academic self-efficacy in college students,350 students were measured with academic emotions questionnaire and academic self-efficacy questionnaire respectively.The results indicated that:①The score of academic emotions of college students was higher than mean score.②The depressions of girls’were higher than boys’.The college students in grade one were obviously higher than the students of grade three on the anxiety;were higher than the students of grade two on the upset.③The different academic self-efficacy levels in college students had significantly difference with academic emotions.Academic self-efficacy had significant correlation with all dimensions of academic emotions.④ Stepwise regression analysis revealed that academic self-efficacy was predictors of the academic emotions.The academic self-efficacy of the school students is useful to enhance and maintain their academic emotions.